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Super aligned carbon nanotubes for interfacial modification of hole transport layer in polymer solar cells

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dc.creator Ali, Abid
dc.creator Bozar, Sinem
dc.creator Günes, Serap
dc.creator Asghar, Muhammad Adeel
dc.creator Alwadai, Norah
dc.creator Akyürekli, Salih
dc.creator Kazici, Mehmet
dc.creator Shahbaz, Muhammad
dc.creator KESKİN, Bahadır
dc.creator Iqbal, Munawar
dc.creator Ahmad, Azhar
dc.creator Kahveci, Cihangir
dc.creator Kaleli, Murat
dc.date 2023-04-01T00:00:00Z
dc.date.accessioned 2025-02-25T10:41:02Z
dc.date.available 2025-02-25T10:41:02Z
dc.identifier ec8a7559-c325-4881-bf73-22d38222a47a
dc.identifier 10.1016/j.susmat.2023.e00569
dc.identifier https://avesis.sdu.edu.tr/publication/details/ec8a7559-c325-4881-bf73-22d38222a47a/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/101832
dc.description © 2023This work presents a facile and innovative method for the insertion of super aligned carbon nanotubes (CNTs) as sheets over and within poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) as an efficient hole transport layer (HTL) in the inverted type polymer solar cell. CNTs sheets drawn from the vertically grown CNTs arrays were extracted via a sharp-edge blade and were directly transferred to the surface of PEDOT:PSS followed by the deposition of thermally evaporated silver electrode. All the characteristic photovoltaic parameters of the device have been improved with the insertion of special patterened CNTs sheets as compared to the standards device (without CNTs sheets). Power conversion efficiency (PCE) improved from 2.14% to 3.69% with the increased short circuit current density from 9.12 mAcm−2 to 11.58 mAcm−2 and fill factor from 0.48 to 0.58, respectively. Scanning electron microscopy (SEM) images revealed the successful insertion of CNTs without any destructive impact on the integrity of CNTs structure. Moreover, the performance and stability of the device have also been optimized by increasing the thickness of CNTs sheets. Electrochemical impedance spectroscopy (EIS) showed the reduction in charge transfer resistance on replacement of CNTs sheets-modified PEDOT:PSS as HTL as compared to simple PEDOT:PSS, which may be attributed to the creation of ordered steps which provided cascade routes for the better charge (holes) collection. Facile modification of the anode materials with improved device performance for designing of new device architecture will help scale-up production of low-cost, stable, and efficient polymer solar cells.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Super aligned carbon nanotubes for interfacial modification of hole transport layer in polymer solar cells
dc.type info:eu-repo/semantics/article


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