| dc.creator |
TEZEREN, Mustafa A. |
|
| dc.creator |
DILEK, Omer |
|
| dc.creator |
TİLKİ, Tahir |
|
| dc.creator |
ERTURK, Erkan |
|
| dc.date |
2018-01-10T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T09:24:50Z |
|
| dc.date.available |
2020-10-06T09:24:50Z |
|
| dc.identifier |
0e7d655a-8b25-4d20-b937-07bf4a94a08b |
|
| dc.identifier |
10.1016/j.tet.2017.11.054 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/0e7d655a-8b25-4d20-b937-07bf4a94a08b/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/53309 |
|
| dc.description |
Efficient and modular syntheses of chiral 2-(2-hydroxyaryl)alcohols (HAROLs), novel 1,4-diols carrying one phenolic and one alcohol hydroxyl group, have been developed which led to generation of a small library of structurally diverse HAROL5 in enantiomerically pure form: Of the different HAROLs examined, a HAROL based on the indan backbone exhibited the highest activity and enantioselectivity in the 1,2-addition of certain organometallic compounds to aldehydes in the presence of Ti((OPr)-Pr-i)(4) (up to 97% y, 88% ee) and performed as a hydrogen-bond donor organocatalyst in the Morita-Baylis-Hillman reaction, promoted by trialkylphosphines. (C) 2017 Elsevier Ltd. All rights reserved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Chiral 2-(2-hydroxyaryl)alcohols (HAROLs) with a 1,4-diol scaffold as a new family of ligands and organocatalysts |
|
| dc.type |
info:eu-repo/semantics/article |
|