| dc.creator |
ENGİN, MEHMET SONER |
|
| dc.creator |
SAYIN, SERKAN |
|
| dc.creator |
ÇAY, SEYDAHMET |
|
| dc.creator |
KIR, Esengül |
|
| dc.creator |
Sardohan-Koseoglu, Tugba |
|
| dc.date |
2019-05-17T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T09:27:43Z |
|
| dc.date.available |
2020-10-06T09:27:43Z |
|
| dc.identifier |
1af910ff-bceb-46e4-ac3a-31412f41c91e |
|
| dc.identifier |
10.1080/03067319.2019.1616706 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/1af910ff-bceb-46e4-ac3a-31412f41c91e/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/54574 |
|
| dc.description |
Here in we report the syntheses of the thiol functionalised p-tert-butylcalix[4]arene from the reaction of p-tert-butylcalix[4]arene-dialkylbromide derivative with thiourea. The structure of the thiol functionalised p-tert-butylcalix[4]arene was determined by using (HNMR)-H-1, (CNMR)-C-13 and elemental analysis techniques. Furthermore, the thiol functionalised p-tert-butylcalix[4]arene, cellulose triacetate (CTA) and 2-nitrophenyl octyl ether (o-NPPE) in dichloromethane were used to make a new calixarene-embedded polymer inclusion membrane (Bu-t-C@PIM). The surface and structure morphology of Bu-t-C@PIM was detected using thermogravimetric analysis, elemental analysis techniques and scanning electron microscopy. The affinity (the percentage of metal ion transferred from the source solution) of a PIM towards a range of divalent cations was found to follow the order Pb2+ > Zn2+ > Ni2+ > Cu2+ > Cd2+ > Co2+. The results also indicated that the transport efficiency of Bu-t-C@PIM was repeatable and may be beneficial in the development of a simplistic and highly influential trace metal recovery method from aqueous solution. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Preparation and characterisation of thiol functionalised p-tert-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity |
|
| dc.type |
info:eu-repo/semantics/article |
|