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Mn(III)acetate-mediated additions of active methylene compounds to bicyclic olefins: Synthesis of bicyclic olefin-fused dihydrofurans

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dc.creator Alabas, Bahadir
dc.creator ÇALIŞKAN, Raşit
dc.date 2019-10-17T21:00:00Z
dc.date.accessioned 2020-10-06T09:29:34Z
dc.date.available 2020-10-06T09:29:34Z
dc.identifier 1c78893b-1eac-4785-ba4c-a32c0a36aa5a
dc.identifier 10.1016/j.tet.2019.130572
dc.identifier https://avesis.sdu.edu.tr/publication/details/1c78893b-1eac-4785-ba4c-a32c0a36aa5a/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/54722
dc.description Bicyclic alkenes such as benzonorbornadiene, oxabenzonorbornadiene, norbornene, and norbornadiene were reacted with 1,3-cyclohexanedione and ethyl acetoacetate in the presence of Mn(OAc)(3) and Cu(OAc)(2). Except for the reaction of benzonorbornadiene and ethyl acetoacetate, dihydrofuran derivatives were the only products obtained. The formation of naphthalene derivatives was observed together with dihydrofuran in the aforementioned benzonorbornadienefethyl acetoacetate reaction. Additionally, the dihydrofuran product from the addition of ethyl acetoacetate to norbornadiene was slowly converted into epoxide derivative with air. The mechanism for the formation of the products is discussed. (C) 2019 Elsevier Ltd. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Mn(III)acetate-mediated additions of active methylene compounds to bicyclic olefins: Synthesis of bicyclic olefin-fused dihydrofurans
dc.type info:eu-repo/semantics/article


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