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Removal of Cr(III) and Cu(II) using poly(2-chloroaniline)/polyvinylidenefluoride composite cation-exchange membranes by Donnan dialysis

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dc.creator KIR, Esengül
dc.creator Percin Ozkorucuklu, Sabriye
dc.creator Sardohan Koseoglu, Tugba
dc.creator Karamizrak, Esin
dc.date 2012-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T09:30:06Z
dc.date.available 2020-10-06T09:30:06Z
dc.identifier 20a15ac5-622a-483a-bec0-bfece50e9d29
dc.identifier 10.3906/kim-1204-74
dc.identifier https://avesis.sdu.edu.tr/publication/details/20a15ac5-622a-483a-bec0-bfece50e9d29/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/55127
dc.description P2ClAn/PVDF composite membranes were prepared utilizing cation-exchange groups in the PVDF (polyvinylidenefluoride) membrane matrix by casting method. The poly(2-chloroaniline) (P2ClAn) was chemically synthesized with different dopant anions such as o-aminobenzene sulfonic acid (ABS) and sodium dodecyl sulfate (SDS). P2ClAn/PVDF membranes were extensively characterized for their surface morphology, thickness, ion-exchange capacity, SEM, AFM, and FTIR-ATR measurements. The SEM, AFM and FTIR-ATR pictures, comparing the original PVDF membrane support sheet to P2ClAn/PVDF composite membranes, indicate that the morphologies of the membranes are different. The membrane potential measurements were performed in various electrolyte solutions in order to observe the selectivity and stability of these membranes at different pHs. The P2ClAn/PVDF cation-exchange membranes were then used for the removal of chromium(III) and copper(II) ions from aqueous solution with Donnan dialysis. The flux values (J) of chromium(III) and copper(II) were obtained. The flux value of copper(II) ion was higher than chromium(III) for all of composite membranes because of the hydration volume.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Removal of Cr(III) and Cu(II) using poly(2-chloroaniline)/polyvinylidenefluoride composite cation-exchange membranes by Donnan dialysis
dc.type info:eu-repo/semantics/article


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