| dc.creator |
Sezer, Serdar |
|
| dc.creator |
ŞAHİN, Ertan |
|
| dc.creator |
TANYELİ, CİHANGİR |
|
| dc.date |
2010-03-15T22:00:00Z |
|
| dc.date.accessioned |
2020-10-06T09:30:15Z |
|
| dc.date.available |
2020-10-06T09:30:15Z |
|
| dc.identifier |
21df5a68-9ba4-4b3d-838d-d25fce704a75 |
|
| dc.identifier |
10.1016/j.tetasy.2010.02.016 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/21df5a68-9ba4-4b3d-838d-d25fce704a75/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/55248 |
|
| dc.description |
An intramolecular Pauson-Khand reaction of enynes derived from homoallyl, homopropargyl, and allyl alcohols is described. 2-Heteroaryl-substituted homoallyl, homopropargyl, and allyl alcohols are easily and efficiently resolved through enzymatic resolution in high ee (91-99%) and with a known stereochemistry. Each enantiomerically enriched enyne derived from homoallyl and homopropargyl alcohols affords the conformationally most stable diastereomeric cyclopenta[c]pyran ring system as the sole product, whereas enantiomerically enriched enynes derived from allyl alcohols give a diastereomeric cis:trans mixture of the cyclopenta[c]furan ring system. (C) 2010 Elsevier Ltd. All rights reserved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Stereoselective synthesis of optically active cyclopenta[c]pyrans and cyclopenta[c]furans by the intramolecular Pauson-Khand reaction |
|
| dc.type |
info:eu-repo/semantics/article |
|