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Synthesis and Photophysical Characterizations of Thermal -Stable Naphthalene Benzimidazoles

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dc.creator Erten-Ela, Sule
dc.creator Ozcelik, Serdar
dc.creator Eren, Esin
dc.date 2011-06-30T21:00:00Z
dc.date.accessioned 2020-10-06T09:30:21Z
dc.date.available 2020-10-06T09:30:21Z
dc.identifier 22af3b50-43e6-4dd5-bd7f-4af2571aeb3a
dc.identifier 10.1007/s10895-011-0845-z
dc.identifier https://avesis.sdu.edu.tr/publication/details/22af3b50-43e6-4dd5-bd7f-4af2571aeb3a/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/55340
dc.description Microwave-assisted synthesis, photophysical and electrochemical properties of thermal-stable naphthalene benzimidazoles and naphthalimides are studied in this paper. Microwave-assisted synthesis of naphthalene benzimidazoles provide higher yields than the conventional thermal synthesis. Comparative photophysical properties of naphthalene benzimidazoles and naphthalimides are revealed that conjugation of electron-donating group onto naphthalimide moiety increases fluorescence quantum yields. Fluorophore-solvent interactions are also investigated using Lippert-Mataga equation for naphthalimides and naphthalene benzimidazoles. Thermal stabilities of naphthalene benzimidazoles are better than naphthalimides due to increased aromaticity. The experimental E-LUMO levels of naphthalene benzimidazoles are found to be between 3.15 and 3.28 eV. Therefore, naphthalene benzimidazole derivatives consisting of anchoring groups are promising materials in organic dye sensitized solar cells.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis and Photophysical Characterizations of Thermal -Stable Naphthalene Benzimidazoles
dc.type info:eu-repo/semantics/article


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