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Total Synthesis of Olivacine and Ellipticine via a Lactone Ring Opening and Aromatization Cascade

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dc.creator Dilek, Omer
dc.creator Patir, Suleyman
dc.creator TİLKİ, Tahir
dc.creator Erturk, Erkan
dc.date 2019-06-20T21:00:00Z
dc.date.accessioned 2020-10-06T09:35:47Z
dc.date.available 2020-10-06T09:35:47Z
dc.identifier 2802a95b-956b-4afe-b35f-9bb53c4acb8b
dc.identifier 10.1021/acs.joc.9b00706
dc.identifier https://avesis.sdu.edu.tr/publication/details/2802a95b-956b-4afe-b35f-9bb53c4acb8b/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/55877
dc.description Effective preparation of olivacine and ellipticine via late-stage D-ring cyclization is described. Key features of the synthetic routes include trifluoroacetic acid-mediated formation of a lactone that is fused to a tetrahydrocarbazole derivative and its one-pot two-step ring opening and aromatization mediated by para-toluenesulfonic acid and palladium on carbon, respectively.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Total Synthesis of Olivacine and Ellipticine via a Lactone Ring Opening and Aromatization Cascade
dc.type info:eu-repo/semantics/article


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