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Synthesis, acidity and antioxidant properties of some novel 3,4-disubstituted-4,5-dihydro-1H-1,2,4-triazol-5-one derivatives

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dc.creator Alkan, Muzaffer
dc.creator Yuksek, Haydar
dc.creator Gursoy-Kol, Ozlem
dc.creator Calapoglu, Mustafa
dc.date 2007-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T09:36:08Z
dc.date.available 2020-10-06T09:36:08Z
dc.identifier 2ac18fed-db3b-4e1b-9b15-6e18462d5740
dc.identifier 10.3390/molecules13010107
dc.identifier https://avesis.sdu.edu.tr/publication/details/2ac18fed-db3b-4e1b-9b15-6e18462d5740/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/56149
dc.description 3-Alkyl(aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5-ones 2a-g reacted with 4-diethylaminobenzaldehyde to afford the corresponding 3-alkyl(aryl)-4-(4-diethylaminobenzylidenamino)-4,5-dihydro-1H-1,2,4-triazol-5-ones 3a-g. The acetylation reactions of compounds 3a-e were investigated and compounds 4a-e were thus obtained. The new compounds were characterized using IR, H-1-NMR, C-13-NMR, UV and MS spectral data. In addition, the newly synthesized compounds 3a-g were titrated potentiometrically with tetrabutylammonium hydroxide in four non-aqueous solvents such as isopropyl alcohol, tert-butyl alcohol, acetone and N,N-dimethylformamide (DMF), and the half-neutralization potential values and the corresponding pK(a) values were determined for all cases. Moreover, 3 and 4 type compounds were also screened for their antioxidant activities.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis, acidity and antioxidant properties of some novel 3,4-disubstituted-4,5-dihydro-1H-1,2,4-triazol-5-one derivatives
dc.type info:eu-repo/semantics/article


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