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Development a Spectrophotometric of Fe(III), Al(III) and Cu(II) Using Eriochrome Cyanine R Ligand and Assessment of the Obtained Data by Partial Least-Squares and Artificial Neural Network Method-Application to Natural Waters

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dc.creator AKTAŞ, Ahmet Hakan
dc.date 2018-07-31T21:00:00Z
dc.date.accessioned 2020-10-06T09:36:26Z
dc.date.available 2020-10-06T09:36:26Z
dc.identifier 2d4c51aa-5320-41ae-bac4-6bea1b25f8a4
dc.identifier 10.3964/j.issn.1000-0593(2018)08-2638-07
dc.identifier https://avesis.sdu.edu.tr/publication/details/2d4c51aa-5320-41ae-bac4-6bea1b25f8a4/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/56382
dc.description Simultaneous determination of heavy metal cations and accurate quantitative prediction of them are of great interest in analytical chemistry. This work has focused on a comprehensive comparison of partial least squares (PLS-1) and artificial neural networks (ANN) as two types of chemometric methods. For this purpose, aluminum, iron and copper were studied as three analytes whose UV-Vis absorption spectra highly overlap each other. Accordance with determined parameters ( ligand concentration, pH, waiting times, the relationship between absorbance and concentration of metal ion effect and foreign ions) are provided and the optimum conditions. After establishing the optimum conditions for Fe3+, Al3+ and Cu2+ containing mixtures spectrophotometric determinations and the data calibration method of least squares (PLS-1) regression, and artificial neural network (ANN) methods were used. Chemometric methods are applied in a fast, simple, and the results are applicable.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Development a Spectrophotometric of Fe(III), Al(III) and Cu(II) Using Eriochrome Cyanine R Ligand and Assessment of the Obtained Data by Partial Least-Squares and Artificial Neural Network Method-Application to Natural Waters
dc.type info:eu-repo/semantics/article


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