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Carbon-carbon bond formation catalyzed by PEPPSI Pd-NHC

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dc.creator Akkoc, Senem
dc.creator İLHAN, İLHAN ÖZER
dc.creator GÖK, YETKİN
dc.creator Kayser, Veysel
dc.date 2017-04-30T21:00:00Z
dc.date.accessioned 2020-10-06T09:36:29Z
dc.date.available 2020-10-06T09:36:29Z
dc.identifier 2d9fc0d1-fded-4823-9a17-9fc155fff0c8
dc.identifier 10.1016/j.ica.2017.01.025
dc.identifier https://avesis.sdu.edu.tr/publication/details/2d9fc0d1-fded-4823-9a17-9fc155fff0c8/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/56417
dc.description Five new palladium complexes were efficiently synthesized from the reaction of benzimidazolium salts, potassium carbonate (K2CO3) and palladium chloride (PdCl2) in pyridine (for 3-5) or 3-chloropyridine (for 6 and 7). The synthesized complexes were characterized and tested in Suzuki-Miyaura cross-coupling reaction as catalysts. In the presence of catalysts 3-7, biaryl products were obtained in moderate yields when phenylboronic acid was used as boronic acid derivative. However, the coupling of thianaphthene-2-boronic acid with 1-chloro-4-nitrobenzene generated low yields although a longer period of time was used in comparison to the coupling of phenylboronic acid with aryl chlorides. (C) 2017 Elsevier B.V. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Carbon-carbon bond formation catalyzed by PEPPSI Pd-NHC
dc.type info:eu-repo/semantics/article


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