| dc.creator |
Dilek, Omer |
|
| dc.creator |
Tezeren, Mustafa Ali |
|
| dc.creator |
Erturk, Erkan |
|
| dc.creator |
TİLKİ, Tahir |
|
| dc.date |
2018-12-31T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T09:47:34Z |
|
| dc.date.available |
2020-10-06T09:47:34Z |
|
| dc.identifier |
39b9a030-c9e9-498a-8c02-57537bb3b7a2 |
|
| dc.identifier |
10.3906/kim-1810-78 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/39b9a030-c9e9-498a-8c02-57537bb3b7a2/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/57649 |
|
| dc.description |
Starting from a chiral secondary alcohol, novel enantiopure 1,4-aminoalkylphenols (AAPs) were prepared by exploiting conventional organic transformations such as the Mitsunobu reaction, Eschweiler-Clarke N-methylation, and demethylation of anisoles. The catalytic activity of the 1,4-AAPs was investigated in enantioselective Et2Zn addition to benzaldehyde. They were found to accelerate the Et2Zn addition to benzaldehyde. High yields and enantioselectivities (e.g., 95% yield and 82% ee) were achieved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Chiral 1,4-aminoalkylphenols for enantioselective diethylzinc addition to aldehydes |
|
| dc.type |
info:eu-repo/semantics/article |
|