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Dehydration, Water Vapor Adsorption and Desorption Behavior of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)]

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dc.creator Gonen, Mehmet
dc.creator Alp, Burcu
dc.creator Savrik, Sevdiye Atakul
dc.creator Balkose, Devrim
dc.creator Ulku, Semra
dc.date 2011-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T09:48:39Z
dc.date.available 2020-10-06T09:48:39Z
dc.identifier 41d772f1-b575-42cd-a4f7-d0d2ccdaeec1
dc.identifier 10.1080/07373937.2012.701258
dc.identifier https://avesis.sdu.edu.tr/publication/details/41d772f1-b575-42cd-a4f7-d0d2ccdaeec1/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/58461
dc.description The dehydration behaviors of two different hydrated zinc borate species, Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)], which are industrially important flame retardants, were studied by thermal gravimetric(TG) analysis and in situ diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. Dehydration onset temperatures of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)] were 129 and 320 degrees C, respectively, at a 10 degrees C/min ramp rate. A very small amount of boric acid was volatilized in addition to water vapor when both samples were heated at 250 degrees C. A significant amount of water vapor was adsorbed by Zn[B3O3(OH)(5)] center dot H2O from air at 25 degrees C. However, Zn[B3O4(OH)(3)] adsorbed a very small amount of water under the same conditions. Both zinc borates did not have a tendency to cake during storage.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Dehydration, Water Vapor Adsorption and Desorption Behavior of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)]
dc.type info:eu-repo/semantics/article


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