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4-Carboxybiphenyl and thiophene substituted porphyrin derivatives for dye-sensitized solar cell

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dc.creator ÇOĞAL, SADIK
dc.creator ERTEN ELA, ŞULE
dc.creator OCAKOĞLU, KASIM
dc.creator ÖKSÜZ, Ayşegül
dc.date 2015-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T09:50:03Z
dc.date.available 2020-10-06T09:50:03Z
dc.identifier 4c4a768b-d0b8-443d-b53a-4e61398ca6dc
dc.identifier 10.1080/15421406.2016.1184383
dc.identifier https://avesis.sdu.edu.tr/publication/details/4c4a768b-d0b8-443d-b53a-4e61398ca6dc/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/59520
dc.description Porphyrin sensitizer (Por) containing 4-carboxybiphenyl and 2-thienyl and its metallated Zn(II) derivative (ZnPor) were synthesized and investigated. The porphyrin dyes were characterized by MALDI-MS, H-1 NMR, UV-vis, fluorescence and cyclic voltammetry methods. It was found that using of biphenyl bridge between anchoring group and porphyrin core enhanced the conjugation length of the porphyrin macrocycle. The new porphyrin dyes were used as sensitizers in dye-sensitized solar cells (DSSCs). ZnPor-based dye sensitized solar cells yielded a short circuit photocurrent density of 3.98 mA cm(-2), an open circuit voltage of 500 mV, and a fill factor of 0.67, corresponding to an overall conversion efficiency (eta) of 1.33%.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title 4-Carboxybiphenyl and thiophene substituted porphyrin derivatives for dye-sensitized solar cell
dc.type info:eu-repo/semantics/article


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