| dc.creator |
Yuan, Mengwei |
|
| dc.creator |
Sahin, Selmihan |
|
| dc.creator |
Cai, Rong |
|
| dc.creator |
Minteer, Shelley D. |
|
| dc.creator |
Hickey, David P. |
|
| dc.creator |
Milton, Ross D. |
|
| dc.creator |
Abdellaoui, Sofiene |
|
| dc.date |
2018-05-27T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T10:24:19Z |
|
| dc.date.available |
2020-10-06T10:24:19Z |
|
| dc.identifier |
5cbae0e1-7c45-4513-95f4-4595a4cd9c0c |
|
| dc.identifier |
10.1002/anie.201803397 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/5cbae0e1-7c45-4513-95f4-4595a4cd9c0c/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/61185 |
|
| dc.description |
Increasing greenhouse gas emissions have resulted in greater motivation to find novel carbon dioxide (CO2) reduction technologies, where the reduction of CO2 to valuable chemical commodities is desirable. Molybdenum-dependent,formate dehydrogenase (Mo-FDH) from Escherichia coli is a metalloenzyme that is able to interconvert formate and CO, We describe a low-potential redox polymei; synthesized by a facile method, that contains cobaltocene (grafted to poly(allylumine), Cc-PAA) to simultaneously mediate electrons to Mo-FDH and immobilize Mo-FDH at the surface of carbon electrode. The resulting bioelectrode reduces CO2 to formate with a high Faradaic efficiency of 991 +/- 5 % at a mild applied potential of -0.66 V vs. SHE. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Creating a Low-Potential Redox Polymer for Efficient Electroenzymatic CO2 Reduction |
|
| dc.type |
info:eu-repo/semantics/article |
|