| dc.creator |
Akkoc, Senem |
|
| dc.creator |
İLHAN, İLHAN ÖZER |
|
| dc.creator |
Kayser, Veysel |
|
| dc.creator |
GÖK, YETKİN |
|
| dc.date |
2016-01-14T22:00:00Z |
|
| dc.date.accessioned |
2020-10-06T10:25:18Z |
|
| dc.date.available |
2020-10-06T10:25:18Z |
|
| dc.identifier |
64489066-8a79-40a8-8ab4-76973e86115c |
|
| dc.identifier |
10.3762/bjoc.12.9 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/64489066-8a79-40a8-8ab4-76973e86115c/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/61923 |
|
| dc.description |
A series of novel benzimidazolium salts (1-4) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes [ PdCl2(NHC)(Py)] (5-8), where NHC = 1-(N-methylphthalimide)3- alkylbenzimidazolin-2-ylidene and Py = 3-chloropyridine, were synthesized and characterized by means of H-1 and C-13{H-1} NMR, UV-vis (for 5-8), ESI-FTICR-MS (for 2, 4, 6-8) and FTIR spectroscopic methods and elemental analysis. The synthesized compounds were tested in Suzuki-Miyaura cross-coupling (for 1-8) and arylation (for 5-8) reactions. As catalysts, they demonstrated a highly efficient route for the formation of asymmetric biaryl compounds even though they were used in very low loading. For example, all compounds displayed good catalytic activity for the C-C bond formation of 4-tert-butylphenylboronic acid with 4-chlorotoluene. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
N-Methylphthalimide-substituted benzimidazolium salts and PEPPSI Pd-NHC complexes: synthesis, characterization and catalytic activity in carbon-carbon bond-forming reactions |
|
| dc.type |
info:eu-repo/semantics/article |
|