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High-performance Flexible Complementary Electrochromic Device Based on Plasma Modified WO3 Nano Hybrids and V2O5 Nanofilm with Low Operation Voltages

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dc.creator ALVER, Ceyda
dc.creator Karaca, Gozde Yurdabak
dc.creator UYGUN, Emre
dc.creator ÖKSÜZ, Lütfi
dc.creator Oksuz, Ayşegül
dc.creator EREN, Esin
dc.date 2018-08-31T21:00:00Z
dc.date.accessioned 2020-10-06T10:32:20Z
dc.date.available 2020-10-06T10:32:20Z
dc.identifier 73970630-9080-4f46-97b3-67ba7275e875
dc.identifier 10.1002/elan.201800276
dc.identifier https://avesis.sdu.edu.tr/publication/details/73970630-9080-4f46-97b3-67ba7275e875/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/63456
dc.description Tungsten trioxide-poly(3,4-ethylenedioxythiophene) (WO3-PEDOT) and tungsten trioxide-polyfuran (WO3-PFu) were prepared by rf rotating plasma polymerization. Electrochromic hybrid thin films were fabricated onto flexible polyethylene terephthalate (PET)/ indium tin oxide (ITO) film using electron beam evaporation method. In order to deeply characterize all films, scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) and electrochemical impedance spectroscopy (EIS) techniques were used. The counter electrode effect on plasma modified WO3 nano hybrids-based electrochromic devices (ECDs) was evaluated. By incorporating flexible vanadium pentoxide (V2O5) film as counter electrode, complementary ECDs were constructed through combining the hybrid flexible films (WO3-PEDOT, WO3-PFu) as working electrodes, which exhibit highly efficient electrochromic performance with low voltage operation. Especially, WO3-PEDOT/V2O5-based ECD owns a high optical modulation of 61.5% at 750nm driven by -1.0V (coloration) and +1V (bleaching) with fast response times (coloration time: 13.58s, bleaching time: 8.07s) and a high coloration efficiency of 527cm(2)C(-1). This study can supply useful and efficient avenue for designing flexible complementary electrochromic device for energy-saving flexible electronics.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title High-performance Flexible Complementary Electrochromic Device Based on Plasma Modified WO3 Nano Hybrids and V2O5 Nanofilm with Low Operation Voltages
dc.type info:eu-repo/semantics/article


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