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Biofilms from micro/nanocellulose of NaBH4-modified kraft pulp

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dc.creator TOZLUOĞLU, AYHAN
dc.creator POYRAZ, BAYRAM
dc.creator CANDAN, ZEKİ
dc.creator YAVUZ, Mustafa
dc.creator ARSLAN, Recai
dc.date 2017-07-31T21:00:00Z
dc.date.accessioned 2020-10-06T10:32:36Z
dc.date.available 2020-10-06T10:32:36Z
dc.identifier 75afac1c-442d-4e5f-ab3e-99f6e7f5ca0c
dc.identifier https://avesis.sdu.edu.tr/publication/details/75afac1c-442d-4e5f-ab3e-99f6e7f5ca0c/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/63658
dc.description
dc.description <p>Industrial applications of microfibrillated cellulose (MFC) and nanofibrillated cellulose (NFC) have been in<br />use for some time however, there is a need to improve the production steps and at the same time to obtain better quality<br />products. NFC and MFC were generated from NaBH4-modified kraft pulp, produced from a red gum tree plant (Eucalyptus<br />camaldulensis). The generated NFC and MFC were characterized by high-performance liquid chromatography, Fourier<br />transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA) and 13C-nuclear magnetic resonance (NMR).<br />Morphological and viscoelastic properties were investigated by scanning electron microscopy and rheometry, respectively.<br />The storage moduli of biofilms produced from NFC and MFC were investigated by dynamic mechanical thermal analysis<br />(DMTA). Both exhibited mostly identical FTIR spectra. When the spectra were compared with those of NaBH4-modified<br />kraft pulp, minor shifts were observed due to crystallinity. In NMR spectra, disordered cellulose structures were observed<br />for both NFC and MFC, and these findings were also confirmed by differential scanning calorimetry. Rheology studies<br />revealed that the lowest viscosity was observed with MFC. TGA results showed that NFC degraded earlier compared with<br />NaBH4-modified kraft pulp. DMTA exhibited that NFC films had about six times higher storage modulus compared with<br />MFC.</p>
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Biofilms from micro/nanocellulose of NaBH4-modified kraft pulp
dc.type info:eu-repo/semantics/article


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