| dc.creator |
ÇALIŞKAN, Raşit |
|
| dc.creator |
YILIMAZ, Ozlem |
|
| dc.creator |
Balci, Metin |
|
| dc.creator |
Nohut, Neslihan |
|
| dc.creator |
ŞAHİN, Ertan |
|
| dc.date |
2017-01-25T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T10:33:28Z |
|
| dc.date.available |
2020-10-06T10:33:28Z |
|
| dc.identifier |
7c6976e5-ed74-40ea-b4f7-aff1b78f7390 |
|
| dc.identifier |
10.1016/j.tet.2016.11.061 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/7c6976e5-ed74-40ea-b4f7-aff1b78f7390/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/64315 |
|
| dc.description |
Benzonorbornadiene and 7-oxabenzonorbornadiene were reacted with Meldrum's acid and dimethyl malonate in the presence of Mn(OAc)(3) and Cu(OAc)(2) in acetic acid. The reaction of benzonorbornadiene with Meldrum's acid gave a naphthalene derivative whereas the reaction with dimethyl malonate formed rearranged products derived from a carbocation intermediate. However, the reaction of 7-oxabenzonorbornadiene with Meldrum's acid gave two nonrearranged products. On the other hand, the reaction with dimethyl malonate unexpectedly formed a dihydronapthalene derivative with an unusual structure. The mechanism for the formation of the products is discussed. (C) 2016 Elsevier Ltd. All rights reserved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Unusual manganese(III)-mediated oxidative free-radical additions of Meldrum's acid and dimethyl malonate to benzonorbornadiene and oxabenzonorbornadiene |
|
| dc.type |
info:eu-repo/semantics/article |
|