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Some Novel Conducting Polythiophene Derivatives: Theoretical Analysis, Synthesis, Characterization and Electroreological Properties

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dc.creator Uygun, Aysegul
dc.creator Sen, Songul
dc.creator Aytemiz, Nevin
dc.creator TİLKİ, Tahir
dc.creator Yavuz, Ayse Gul
dc.creator Maslakci, Zafer
dc.creator Karabacak, Cigdem
dc.creator YAVUZ, Mustafa
dc.date 2009-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T10:47:35Z
dc.date.available 2020-10-06T10:47:35Z
dc.identifier 8870395b-deaf-4daa-b9f7-0ff84f37fcdc
dc.identifier 10.1080/10601321003659655
dc.identifier https://avesis.sdu.edu.tr/publication/details/8870395b-deaf-4daa-b9f7-0ff84f37fcdc/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/65537
dc.description A series of alternating phylene and symmetrically bithiophene containing repeat units and the respective homopolymers have been synthesized and characterized by combining FTIR, UV-Vis spectroscopy, four probe conductivity measurement, TGA and SEM analysis. Quantum mechanical calculations of the structures and infrared spectra of the monomers and respective dimers were compared with experimental results. The polymers are soluble in N-methyl-pyrrolidone (NMP). The samples have conductivities of 10(-5) S/cm levels. Thermal degradation analysis results indicated that poly-bithiophene derivatives have higher thermal stabilities than poly-monothiophene derivatives. All samples exhibited different surface morphologies. The electrorheological (ER) properties of polymer suspensions in silicone oil were prepared and ER behavior was investigated as a function of shear rate, electric field strength and frequency.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Some Novel Conducting Polythiophene Derivatives: Theoretical Analysis, Synthesis, Characterization and Electroreological Properties
dc.type info:eu-repo/semantics/article


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