| dc.creator |
TİLKİ, Tahir |
|
| dc.creator |
Erturk, Erkan |
|
| dc.creator |
Erdogan, Tuba |
|
| dc.creator |
Goren, Ahmet C. |
|
| dc.creator |
Tezeren, Mustafa Ali |
|
| dc.date |
2012-04-30T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T10:48:41Z |
|
| dc.date.available |
2020-10-06T10:48:41Z |
|
| dc.identifier |
910a1f8c-ba8a-4548-ac1b-6b39c105b9e6 |
|
| dc.identifier |
10.1002/pi.4141 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/910a1f8c-ba8a-4548-ac1b-6b39c105b9e6/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/66359 |
|
| dc.description |
The readily available mixed-valent iron trifluoroacetate complex [Fe2IIIFeII(mu 3-O)(O2CCF3)6(H2O)3] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.00.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end-group analysis by 19F NMR spectroscopy, a Lewis acid (LA?) catalyzed anionic reaction mechanism is proposed. Copyright (c) 2012 Society of Chemical Industry |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3] |
|
| dc.type |
info:eu-repo/semantics/article |
|