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Factorial experiments for iron removal from kaolin by using single and two-step leaching with sulfuric acid

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dc.creator AKÇİL, Ata Utku
dc.creator TUNCUK, Ayşenur
dc.creator CIFTLIK, S.
dc.date 2013-02-28T22:00:00Z
dc.date.accessioned 2020-10-06T10:49:42Z
dc.date.available 2020-10-06T10:49:42Z
dc.identifier 98cc9696-b504-4e5c-af5f-d6e419dc6eb8
dc.identifier 10.1016/j.hydromet.2013.02.006
dc.identifier https://avesis.sdu.edu.tr/publication/details/98cc9696-b504-4e5c-af5f-d6e419dc6eb8/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/67125
dc.description In the present study, to investigate the effects of acidic leaching on the iron removal from kaolin clay supplied by Cam-Ser Madencilik A.S., the 2(4) full factorial design of experiments and analysis of variance (ANOVA) were performed. The aim of the initial phase of research was to determine the effects of the main and interaction factors which can potentially influence the iron removal process. The factors were; pulp density, sulfuric acid concentration, temperature, leaching duration and reducing agent (oxalic acid, citric acid and hydrogen peroxide) concentration. The highest iron extraction yield (IEY) (26.3%) was obtained after 120 min of treatment at 90 degrees C, 20% pulp density, 3 M H2SO4 and with 0.50 M H2O2 as a reducing agent. For the purpose of increasing the IEY, in the second phase of research, initially the particle size of the kaolin sample was decreased to -106 mu m providing the liberation of iron oxides. Then, two-step leaching experiments were carried out with the optimum leaching conditions of full factorial design tests. The maximum IEY was 37.0% after two-step leaching with the optimum conditions of H2SO4 and H2SO4 with oxalic acid leaching. Iron oxide content of kaolin clay was decreased from 2.40% to 1.51%. (C) 2013 Elsevier B.V. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Factorial experiments for iron removal from kaolin by using single and two-step leaching with sulfuric acid
dc.type info:eu-repo/semantics/article


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