| dc.creator |
ÇALIŞKAN, Raşit |
|
| dc.creator |
Balci, Metin |
|
| dc.creator |
Sari, Ozlem |
|
| dc.date |
2017-08-31T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T10:49:53Z |
|
| dc.date.available |
2020-10-06T10:49:53Z |
|
| dc.identifier |
9a395a6c-1e5f-43f8-af5c-a158b404f73a |
|
| dc.identifier |
10.1002/poc.3720 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/9a395a6c-1e5f-43f8-af5c-a158b404f73a/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/67259 |
|
| dc.description |
3-Chloro-1,2,3,4-tetrahydro-1,4-epoxynaphthalen-2-yl)-3-hydroxy-5,5-dimethylcy-clohex- 2-en-1-one, synthesized by the reaction of oxabenzonorbornadiene with Mn(OAc)(3) and dimedone in the presence of HCl in acetic acid, was submitted to ring-opening reactions with BBr3 and H2SO4. Reaction with BBr3 yielded 2 products, a 5-membered ring and an 8-membered ring, with the former being the major product. However, the H2SO4-supported reaction exclusively formed an 8-membered ring. The mechanism of formation of these products was supported by theoretical calculations. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/openAccess |
|
| dc.title |
Functionalization of oxabenzonorbornadiene: Manganese(III)-mediated oxidative addition of dimedone |
|
| dc.type |
info:eu-repo/semantics/article |
|