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Comparison of Properties and Quartz Crystal Microbalance Measurements of Poly(2-ethylaniline) in the Presence of Surfactants

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dc.creator Uygun, Aysegul
dc.date 2009-12-31T22:00:00Z
dc.date.accessioned 2020-10-06T10:51:06Z
dc.date.available 2020-10-06T10:51:06Z
dc.identifier a39ec3ec-5354-49d4-935b-a5340fef2112
dc.identifier 10.1080/10601325.2010.483350
dc.identifier https://avesis.sdu.edu.tr/publication/details/a39ec3ec-5354-49d4-935b-a5340fef2112/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/68176
dc.description Poly(2-ethylaniline)(P2EANI) films were chemically deposited onto gold electrodes using ammonium persulfate as oxidant in the presence of the surfactants sodium dodecyl sulfate (SDS, anionic), tetradecyltrimethylammonium bromide(TTAB, cationic) and polyoxyethylene octyl phenyl ether(Triton-X 100, non-ionic). The doping and adsorption effects of surfactants onto the properties of P2EANI, were correlated with mass gain, and were determined in situ during polymerization of 2EANI using quartz crystal microbalance (QCM). The frequency shift of P2EANI in the presence of Triton-X 100 was very sharp and fast. TTAB exhibited the lowest frequency and mass shift among the three surfactants. P2EANIs were characterized using FTIR and UV-visible spectroscopies, TGA, conductivity measurements and SEM analysis. The latter technique showed that the polymer morphology is, as expected, affected by the incorporation of surfactants into the polymer.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Comparison of Properties and Quartz Crystal Microbalance Measurements of Poly(2-ethylaniline) in the Presence of Surfactants
dc.type info:eu-repo/semantics/article


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