| dc.creator |
TOKATLI, Ahmet |
|
| dc.creator |
BAHÇELİ, Semiha |
|
| dc.date |
2010-01-31T22:00:00Z |
|
| dc.date.accessioned |
2020-10-06T11:01:46Z |
|
| dc.date.available |
2020-10-06T11:01:46Z |
|
| dc.identifier |
b7dcf4be-89a2-40a6-b857-6d08a8604e3e |
|
| dc.identifier |
10.1088/0031-8949/81/02/025801 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/b7dcf4be-89a2-40a6-b857-6d08a8604e3e/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/70253 |
|
| dc.description |
There are a variety of multi-pulse nuclear magnetic resonance (NMR) experiments for spectral assignment of complex molecules in a solution. The two-dimensional (2D) distortionless enhancement by polarization transfer (DEPT) J-resolved NMR experiment is a C-13-detected, spectral editing polarization transfer technique. The product operator theory is widely used for an analytical description of the multi-pulse NMR experiment for weakly coupled spin systems. In this study, analytical descriptions of the 2D DEPT J-resolved NMR experiment for weakly coupled ISn (I = 1/2, S = 3/2; n = 1, 2, 3) spin systems using the product operator theory have been introduced for the first time. The calculated intensities and positions of the observable signals are simulated for molecules containing [C-13 (I = 1/2), Br-81 (S = 3/2)] nuclei by using a MAPLE program on a computer. Finally, we present a theoretical discussion and experimental suggestions. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Product operator descriptions of the 2D DEPT J-resolved NMR experiment for weakly coupled ISn (I=1/2, S=3/2; n=1, 2, 3) spin systems |
|
| dc.type |
info:eu-repo/semantics/article |
|