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Stereoselective synthesis of spirocyclic cyclopentapyrans by the Pauson-Khand reaction on camphor tethered enynes

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dc.creator Sezer, Serdar
dc.creator Gumrukcu, Yasemin
dc.creator ŞAHİN, Ertan
dc.creator TANYELİ, CİHANGİR
dc.date 2008-11-30T22:00:00Z
dc.date.accessioned 2020-10-06T11:11:32Z
dc.date.available 2020-10-06T11:11:32Z
dc.identifier b815726b-f6f4-4264-96b2-22e548bfd34c
dc.identifier 10.1016/j.tetasy.2008.11.020
dc.identifier https://avesis.sdu.edu.tr/publication/details/b815726b-f6f4-4264-96b2-22e548bfd34c/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/70278
dc.description An intramolecular Pauson-Khand reaction of camphor tethered enynes derived from homoallyl, homomethallyl and homopropargyl alcohols is described. Homoallyl, homomethallyl, and homopropargyl moieties are easily constructed on the camphor carbonyl group with excellent diastereoselectivity due to endo-face selectivity, and with known stereochemistry. Each enantiomerically pure enyne affords the conformationally most stable diastereomeric spirocyclic cyclopenta[c]pyran ring system. (C) 2008 Elsevier Ltd. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Stereoselective synthesis of spirocyclic cyclopentapyrans by the Pauson-Khand reaction on camphor tethered enynes
dc.type info:eu-repo/semantics/article


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