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TEMPO-treated CNF Composites: Pulp and Matrix Effect

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dc.creator Saka, Rasim Cem
dc.creator Poyraz, Bayram
dc.creator Tozluoglu, Ayhan
dc.creator Demir, Ahmet
dc.creator Buyuksari, Umit
dc.creator Fidan, Hakan
dc.creator Unal, H. Ibrahim
dc.creator Candan, Zeki
dc.creator YAVUZ, Mustafa
dc.date 2017-12-31T21:00:00Z
dc.date.accessioned 2020-10-06T11:11:37Z
dc.date.available 2020-10-06T11:11:37Z
dc.identifier b8970511-42a7-4415-a840-05653f12672b
dc.identifier 10.1007/s12221-018-7673-y
dc.identifier https://avesis.sdu.edu.tr/publication/details/b8970511-42a7-4415-a840-05653f12672b/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/70332
dc.description This study examined the effects of matrix (PVA and Si) on the properties of TEMPO-treated nanocomposites preparing from different pulp sources (Kraft and NaBH4 treated Kraft). Chemical characterization and crystallization were determined via FT-IR, thermal stability via TGA and morphological alterations via SEM. UTM and DTMA were used to measure the Young's and storage moduli. The real and imaginary parts of permittivity and electric modulus were evaluated using an impedance analyzer. After interaction, prominent vibrations and alteration of crystallinity were seen. Storage and Young's moduli decreased after Si and PVA interaction. The Si-TOCN films showed higher permittivity properties and all of the films followed a similar trend of significantly dropping epsilon' and epsilon'' values at high frequency. The PVA-TOCN films had mechanical advantages at room temperature compared to the Si-TOCN films. However, the Si-TOCN films had better thermomechanical properties at high temperatures. NaBH4 revealed favorable effects on mechanical properties of the films.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title TEMPO-treated CNF Composites: Pulp and Matrix Effect
dc.type info:eu-repo/semantics/article


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