| dc.creator |
DEDE, Bülent |
|
| dc.creator |
Gorgulu, G. |
|
| dc.date |
2018-01-31T21:00:00Z |
|
| dc.date.accessioned |
2020-10-06T11:21:34Z |
|
| dc.date.available |
2020-10-06T11:21:34Z |
|
| dc.identifier |
ba9af2a3-92f9-417a-8fa6-b72877ce3213 |
|
| dc.identifier |
10.12693/aphyspola.133.239 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/ba9af2a3-92f9-417a-8fa6-b72877ce3213/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/70537 |
|
| dc.description |
We have reported herein the synthesis of a novel quinone derivative ligand containing the Schiff base and its Cu(II) complex starting from 1,4-naphthoquinone. Synthesized compounds were characterized using the Fourier transform infrared, UV-Vis, elemental analysis, inductively coupled plasma optical emission spectrometry, molar conductivity, and magnetic susceptibility measurements. The free ligand was also characterized by H-1- and C-13-NMR spectra. Elemental analyses, stoichiometric and spectroscopic data indicated that the metal: ligand ratio is 1:2 and octahedral structure is proposed for the metal complex of the Schiff base ligand. Computational quantum calculations were also performed using DFT/B3LYP level of theory with 6-311++G(d,p) basis set for the synthesized ligand. It was found that the experimental and theoretical spectroscopic data were consistent. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Synthesis, Characterization and DFT Calculations of 4-((2-Hydroxyethyl)imino)naphthalen-1(4H)-One and its Cu(II) Complex |
|
| dc.type |
info:eu-repo/semantics/article |
|