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Synthesis, structural and optical properties of novel borylated Cu(II) and Co(II) metal complexes of 4-benzylaminobiphenylglyoxime

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dc.creator ILICAN, Saliha
dc.creator KARİPCİN, Fatma
dc.creator ÇAĞLAR, Yasemin
dc.creator ÇAĞLAR, Mujdat
dc.creator SAHIN, Yuecel
dc.creator Dede, Bülent
dc.date 2007-05-14T21:00:00Z
dc.date.accessioned 2020-10-06T11:21:39Z
dc.date.available 2020-10-06T11:21:39Z
dc.identifier bb79bcc3-c32d-4d1b-a4a3-8cb75f2b2f16
dc.identifier 10.1016/j.jorganchem.2007.02.024
dc.identifier https://avesis.sdu.edu.tr/publication/details/bb79bcc3-c32d-4d1b-a4a3-8cb75f2b2f16/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/70604
dc.description 4-Benzylaminobiphenylglyoxime ligand and its Cu(II) and Co(II) complexes were prepared. BF2+-bridge containing 4-benzylaminobiphenylglyoxime complexes were obtained by replacing of the bridging protons of the dioxime complexes with BF2 group. These compounds have been characterized by elemental analysis, spectroscopic (ICP-OES, infra-red) and magnetic susceptibility measurements. Thermal decomposition of the complexes is studied in nitrogen atmosphere. The final decomposition products are found to be the corresponding metal oxides. The optical constants such as optical conductivity, dielectric constant, refractive index were determined for the complexes. The analysis of the optical absorption data revealed that the band gap E-g was direct transitions. The optical dispersion parameters were determined according to Wemple and Didomenico, method. (c) 2007 Elsevier B.V. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis, structural and optical properties of novel borylated Cu(II) and Co(II) metal complexes of 4-benzylaminobiphenylglyoxime
dc.type info:eu-repo/semantics/article


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