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Recovery of vanadium from spent catalysts of sulfuric acid plant by using inorganic and organic acids: Laboratory and semi-pilot tests

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dc.creator ANARBEKOV, Kuanysh
dc.creator BAIKONUROVA, Aliya
dc.creator TUNCUK, Ayşenur
dc.creator BEDELOVA, Zyuldyz
dc.creator ERUST, Ceren
dc.creator Akcil, Ata Utku
dc.date 2016-02-29T22:00:00Z
dc.date.accessioned 2020-10-06T11:22:44Z
dc.date.available 2020-10-06T11:22:44Z
dc.identifier c412d63b-dec1-4cf7-bc0a-9d0840f9dff8
dc.identifier 10.1016/j.wasman.2015.12.002
dc.identifier https://avesis.sdu.edu.tr/publication/details/c412d63b-dec1-4cf7-bc0a-9d0840f9dff8/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/71431
dc.description Catalysts are used extensively in industry to purify and upgrade various feeds and to improve process efficiency. These catalysts lose their activity with time. Spent catalysts from a sulfuric acid plant (main elemental composition: 5.71% V2O5, 1.89% Al2O3, 1.17% Fe2O3 and 61.04% SiO2; and the rest constituting several other oxides in traces/minute quantities) were used as a secondary source for vanadium recovery. Experimental studies were conducted by using three different leaching systems (citric acid with hydrogen peroxide, oxalic acid with hydrogen peroxide and sulfuric acid with hydrogen peroxide). The effects of leaching time, temperature, concentration of reagents and solid/liquid (S/L) ratio were investigated. Under optimum conditions (1:25 S/L. ratio, 0.1 M citric acid, 0.1 M hydrogen peroxide, 50 degrees C and 120 min), 95% V was recovered in the presence of hydrogen peroxide in citric acid leaching. (C) 2015 Elsevier Ltd. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Recovery of vanadium from spent catalysts of sulfuric acid plant by using inorganic and organic acids: Laboratory and semi-pilot tests
dc.type info:eu-repo/semantics/article


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