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Properties of Na-Montmorillonite and Cellulose Nanocrystal Reinforced Poly(butyl acrylate-co-methyl methacrylate) Nanocomposites

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dc.creator Sezer, Serdar
dc.creator Vatansever, Alican
dc.creator Dogan, Hacer
dc.creator Sirkecioğlu, Ahmet
dc.creator Inan, Tulay
dc.date 2015-11-30T22:00:00Z
dc.date.accessioned 2020-10-06T11:23:20Z
dc.date.available 2020-10-06T11:23:20Z
dc.identifier c8643483-4e44-4243-bfe7-630b0df73016
dc.identifier 10.1002/pen.24187
dc.identifier https://avesis.sdu.edu.tr/publication/details/c8643483-4e44-4243-bfe7-630b0df73016/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/71868
dc.description Poly(butyl acrylate-co-methyl methacrylate) (BA-co-MMA) nanocomposite latexes were synthesized in the presence of sodium montmorillonite (Na-MMT) and cellulose nanocrystal (CNC) as fillers. Nanocomposite preparation with 3 wt% Na-MMT based upon the total monomer amount was conducted by semi-batch emulsion polymerization. Furthermore, direct blending of neat copolymer latex with Na-MMT was performed for comparison. CNC/BA-co-MMA nanocomposites were obtained via blending process with varying CNC content (1, 2, and 3 wt %). Good dispersion of both Na-MMT and CNC within the copolymer matrix was achieved as demonstrated by X-ray diffraction and transmission electron microscope. Particle size of the nanocomposite latexes was around 120 nm. Thermal, mechanical, and barrier properties of the copolymer showed great improvement with the addition of both Na-MMT and CNC. CNC nanocomposites displayed enhanced properties with increasing CNC level. Tensile strength of copolymer latex with 3 wt% CNC reached 262.5% of the pristine latex, while tensile strength of Na-MMT nanocomposite at the same content was 187.5% of the pristine latex. (C) 2015 Society of Plastics Engineers
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Properties of Na-Montmorillonite and Cellulose Nanocrystal Reinforced Poly(butyl acrylate-co-methyl methacrylate) Nanocomposites
dc.type info:eu-repo/semantics/article


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