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Electrospun plasma-modified chitosan/poly(ethylene terephthalate)/ferrocenyl-substituted N-acetyl-2-pyrazoline fibers for phosphate anion sensing

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dc.creator Cin, Gunseli Turgut
dc.creator EREN, Esin
dc.creator OKSUZ, Aysegul Uygun
dc.creator Maslakci, Neslihan Nohut
dc.creator Topel, Seda Demirel
dc.date 2016-05-04T21:00:00Z
dc.date.accessioned 2020-10-06T11:24:08Z
dc.date.available 2020-10-06T11:24:08Z
dc.identifier ced09cb7-2d71-41de-bad5-ee9846afc5b2
dc.identifier 10.1002/app.43344
dc.identifier https://avesis.sdu.edu.tr/publication/details/ced09cb7-2d71-41de-bad5-ee9846afc5b2/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/72466
dc.description Two ferrocenyl-substituted N-acetyl-2-pyrazolines, N-acetyl-3-(2-furyl)-5-ferrocenyl-2-pyrazoline (Fc-1) and N-acetyl-3-(2-thienyl)-5-ferrocenyl-2-pyrazoline (Fc-2) electrospun fibers, were produced in the presence of plasma-modified chitosan (PMCh)/poly(ethylene terephthalate) (PET) supporting polymers with an electrospinning method. The morphological and chemical characterizations of the PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers were determined by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis. Thermogravimetric analysis results indicated the presence of ferrocene within the PMCh/PET nanofibers. The electrochemical behavior of the PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers were investigated by cyclic voltammetry measurements based on the ferrocene/ferrocenium redox couple. The new PMCh/PET/Fc-1 and PMCh/PET/Fc-2 electrospun fibers aggregated on the indium tin oxide were used for phosphate anion sensing. The highest oxidation peak currents were observed for the PMCh/PET/Fc-1 electrospun fibers at about 0.56V in 0.1M phosphate buffer. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43344.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Electrospun plasma-modified chitosan/poly(ethylene terephthalate)/ferrocenyl-substituted N-acetyl-2-pyrazoline fibers for phosphate anion sensing
dc.type info:eu-repo/semantics/article


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