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Spectrophotometric determination of pK(a) values for some benzoic acid compounds in acetonitrile-water mixtures

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dc.creator PEKCAN, Guzide
dc.creator Aktas, Ahmet Hakan
dc.date 2006-06-30T21:00:00Z
dc.date.accessioned 2020-10-06T11:25:46Z
dc.date.available 2020-10-06T11:25:46Z
dc.identifier db63f93b-f8c7-4379-bfa3-d176eb6bb3a8
dc.identifier https://avesis.sdu.edu.tr/publication/details/db63f93b-f8c7-4379-bfa3-d176eb6bb3a8/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/73694
dc.description The dissociation pK(a) values of benzoic acid and substituted benzoic acids have been determined in water and acetonitrile-water mixtures (10%, 20%, 30%) by spectrophotometric measurements. The results obtained show that the solvents affect the acid equilibrium. Acetonitrile acts as a strongly differentiating solvent with a modest solvating power for many polar ionic solutes. Linear relationships between pK(a) values in acetonitrile-water mixtures and pK(a) values in pure water have been established for fourteen benzoic acids. rhe pHab is a computer program using the calculation dissociation constants from spectrophotometric data obtained from solutions at known pH.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Spectrophotometric determination of pK(a) values for some benzoic acid compounds in acetonitrile-water mixtures
dc.type info:eu-repo/semantics/article


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