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A Short and Efficient Asymmetric Synthesis of (+/-)-epi-Cytoxazone from cis-(1R,2S,5R)-Menthyl 4-Methoxyphenylglycidates

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dc.creator Coskun, Necdet
dc.creator Er, Mustafa
dc.date 2014-11-30T22:00:00Z
dc.date.accessioned 2020-10-06T11:38:07Z
dc.date.available 2020-10-06T11:38:07Z
dc.identifier e79202d5-ddee-478c-9019-63d4612b3101
dc.identifier 10.1007/s10600-014-1161-z
dc.identifier https://avesis.sdu.edu.tr/publication/details/e79202d5-ddee-478c-9019-63d4612b3101/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/74898
dc.description The racemic epi-cytoxazone was synthesized, starting from p-anisaldehyde, in five steps and 48% overall yield. An efficient synthesis of azido alcohols has been achieved by regioselective ring opening of glycidates using NaN3 in MeOH-H2O. The key step of the process is reductive cyclization of azide carbonates by Zn-TMSCl.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title A Short and Efficient Asymmetric Synthesis of (+/-)-epi-Cytoxazone from cis-(1R,2S,5R)-Menthyl 4-Methoxyphenylglycidates
dc.type info:eu-repo/semantics/article


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