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Product operator descriptions of INEPT and RINEPT NMR spectroscopies for ISn (I=1/2, S=3/2) spin systems

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dc.creator Tokatli, Ahmet
dc.creator BAHÇELİ, SEMİHA
dc.creator GENÇTEN, AZMİ
dc.creator TEZEL, ÖZLEM
dc.creator ŞAHİN, MÜKERREM
dc.date 2004-06-30T21:00:00Z
dc.date.accessioned 2020-10-06T11:38:09Z
dc.date.available 2020-10-06T11:38:09Z
dc.identifier e7b4148e-0e2c-48b1-a8ce-f978ff846353
dc.identifier 10.1016/j.jmr.2004.04.005
dc.identifier https://avesis.sdu.edu.tr/publication/details/e7b4148e-0e2c-48b1-a8ce-f978ff846353/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/74917
dc.description The product operator descriptions of INEPT and reverse INEPT (RINEPT) NMR experiments are introduced for weakly coupled ISn (I = 1/2, S = 3/2 with n = 1, 2, 3) spin systems. Explicit expressions for polarization transfer from spin-3/2 quadrupolar nuclei to spin-1/2 nuclei (and reversed polarization transfer) are given in detail by using the evolutions of product operators under the spin-spin coupling Hamiltonian. The results calculated for the intensities and positions of the observable signals are simulated in the molecules containning the Sn-119 (I = 1/2) and Cl-35 (S = 3/2) nuclei at the coupling constant of J(Sn-Cl) = 375 Hz by using the Maple programme on computer. (C) 2004 Elsevier Inc. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Product operator descriptions of INEPT and RINEPT NMR spectroscopies for ISn (I=1/2, S=3/2) spin systems
dc.type info:eu-repo/semantics/article


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