| dc.creator |
Tilki, Tahir |
|
| dc.creator |
Tezeren, Mustafa Ali |
|
| dc.creator |
Ertürk, Erkan |
|
| dc.date |
2019-10-31T21:00:00Z |
|
| dc.date.accessioned |
2020-10-26T13:12:13Z |
|
| dc.date.available |
2020-10-26T13:12:13Z |
|
| dc.identifier |
019dec84-bb03-4877-aba1-f94575298b1e |
|
| dc.identifier |
10.29233/sdufeffd.649920 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/019dec84-bb03-4877-aba1-f94575298b1e/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/77348 |
|
| dc.description |
<p>In this study, two chiral 2-(2-hydroxyaryl) alcohols (HAROLs; 1,4-diols) and a 1,4-aminoalkylphenol (AAP) were examined as hydrogen-bond donor (HBD) organocatalysts in theasymmetric hetero Diels-Alder (HDA) reaction of aldehydes with Rawal’s diene. Catalyticamount (10 mol%) of the both scaffolds (HAROL and AAP) have been found to effect the HDAreaction in a quite efficient manner. Among them, a HAROL molecule based on indan backbonewas turned out to be the best in terms of catalytic activity and enantioselectivity. On the otherhand, AAP tested seemed to act as a bifunctional organocatalyst, i.e. as both a Lewis base andHBD organocatalyst. Experimental results underpins that a careful tuning of HAROL structuremight lead to the development of more general HBD organocatalysts. <br></p> |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Chiral 1,4-Hydroxyarylalcohols (HAROLs) and 1,4-Aminoalkylphenols (AAPs) as Organocatalysts for Asymmetric Hetero Diels-Alder Reaction |
|
| dc.type |
info:eu-repo/semantics/article |
|