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Anodic stripping voltammetric determination of gold on a polyvinylferrocene coated glassy carbon electrode

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dc.creator Yildiz, A
dc.creator Kavanoz, M
dc.creator Gulce, H
dc.date 2004-01-01T01:00:00Z
dc.date.accessioned 2021-12-03T11:14:48Z
dc.date.available 2021-12-03T11:14:48Z
dc.identifier 097d915a-c13f-40fa-839f-89de1a1b483e
dc.identifier https://avesis.sdu.edu.tr/publication/details/097d915a-c13f-40fa-839f-89de1a1b483e/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/89826
dc.description The anodic stripping voltammetric determination of gold was accomplished on a chemically modified glassy carbon electrode in a solution containing chloride ions. A modifying polymer, polyvinylferrocene, was coated by immersing the glassy carbon surface in its solution in methylene chloride followed by solvent evaporation. Tetrahalo complexes of gold, tetrachloroaurate (III) and tetrabromoaurate (III) ions, were found to be reduced to metallic gold by chemical reduction during immersion of the polymer coated electrode into the solution containing aurate(III) ions. This reaction was utilized as means of preconcentration without the need for cathodic electrolysis prior to the anodic stripping of metallic gold. The effects of the preconcentration period, film thickness and the presence of Cu(II) ions as possible interferants were investigated.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Anodic stripping voltammetric determination of gold on a polyvinylferrocene coated glassy carbon electrode
dc.type info:eu-repo/semantics/article


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