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SYNTHESIS AND COMPLEX-FORMATION OF SUBSTITUTED THIO-GLYOXIMES OF UNSYMMETRICAL VIC-DIOXIMES

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dc.creator SEVINDIR, HC
dc.date 1995-01-01T01:00:00Z
dc.date.accessioned 2021-12-03T11:14:51Z
dc.date.available 2021-12-03T11:14:51Z
dc.identifier 09f75730-41fc-468c-96fa-5fd08028aefe
dc.identifier 10.1080/15533179508014680
dc.identifier https://avesis.sdu.edu.tr/publication/details/09f75730-41fc-468c-96fa-5fd08028aefe/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/89834
dc.description anti-Chloroglyoxime, CGH(2), has been synthesized by chlorination of anti-glyoxime. The reaction of CGH(2) with thiophenol, 4-methyIthiophenol and 4-methoxythiophenol in ethanol between -5 degrees C and -10 degrees C gives unsymmetrical vic-dioximes, designated as thiophenologlyoxime [L(a)H(2)], 4-methylthiophenologlyoxime [L(b)H(2)] and 4-methoxythiophenologlyoxime [L(c)H(2)]. The Cu(II) and Ni(II) complexes of these ligands were prepared and are proposed to be square-planar, while the corresponding Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. Structural assiguments are supported by H-1 NMR, IR and elemental analyses.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title SYNTHESIS AND COMPLEX-FORMATION OF SUBSTITUTED THIO-GLYOXIMES OF UNSYMMETRICAL VIC-DIOXIMES
dc.type info:eu-repo/semantics/article


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