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Kinetic analysis of coupled transport of nitrite ions through liquid membranes at different temperatures

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dc.creator Levent, M
dc.creator Topcu, N
dc.creator Demircioglu, N
dc.creator Kobya, M
dc.date 2000-04-01T00:00:00Z
dc.date.accessioned 2021-12-03T11:19:47Z
dc.date.available 2021-12-03T11:19:47Z
dc.identifier 31bb2afd-6bb0-486b-b0e9-0029faceaaa6
dc.identifier 10.1016/s0015-1882(00)88505-5
dc.identifier https://avesis.sdu.edu.tr/publication/details/31bb2afd-6bb0-486b-b0e9-0029faceaaa6/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/90758
dc.description Non-steady state kinetics of the coupled transport of nitrite (NO2-) ions through liquid membranes (n-hexane 85% + chloroform 15%) containing tetraoctylammonium chloride as a carrier was examined at temperatures ranging from 273-308 degrees K. In this study, the, influence of temperature on the kinetic parameters (k(1d), k(2m), k(2a), t(max), R-m(max), J(d)(max), J(a)(max)) was investigated. The membrane entrance (k(1d)) and exit rates (k(2m), k(2a)) were increased with temperature. For maximum membranes entrance and exit fluxes, the activation energies were calculated from the slopes of the two linear relationships: E-ad = 6.62 kcal/mol and E-aa = 6.63 kcal/mol, respectively. The values of the calculated activation energy indicate that the process is diffusionally controlled.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Kinetic analysis of coupled transport of nitrite ions through liquid membranes at different temperatures
dc.type info:eu-repo/semantics/article


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