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SYNTHESIS AND COMPLEX-FORMATION OF SUBSTITUTED THIO-P-TOLYLGLYOXIMES OF UNSYMMETRICAL VIC-DIOXIMES

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dc.creator SEVINDIR, HC
dc.date 1995-01-01T01:00:00Z
dc.date.accessioned 2021-12-03T11:19:57Z
dc.date.available 2021-12-03T11:19:57Z
dc.identifier 34c384cd-aebf-4324-bf3a-1dcb1e1c9a3d
dc.identifier 10.1080/15533179508218231
dc.identifier https://avesis.sdu.edu.tr/publication/details/34c384cd-aebf-4324-bf3a-1dcb1e1c9a3d/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/90842
dc.description The reaction of anti-p-Tolylchloroglyoxime PTCGH(2) with thiophenol, 4-methylthiophenol and 4-methoxythiophenol in ethanol between -5 degrees C and 10 degrees C gives unsymmetrical vic-dioximes, designated as thiophenolo-p-tolylglyoxime [L(1)H(2)], 4-methylthiophenolo-p-tolylglyoxime [L(2)H(2)] and 4-methoxythiophenol-p-etolylglyoxime [L(3)H(2)]. The Ni(II) and Cu(II) complexes of these ligands are proposed to be square-planar, while the Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. Structural assignments are supported by H-1 NMR IR and elemental analyses which are reported herein.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title SYNTHESIS AND COMPLEX-FORMATION OF SUBSTITUTED THIO-P-TOLYLGLYOXIMES OF UNSYMMETRICAL VIC-DIOXIMES
dc.type info:eu-repo/semantics/article


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