DSpace Repository

Synthesis and characterization of new organocobaloxime derivatives with asymmetric dioxime ligands

Show simple item record

dc.creator KARİPCİN, FATMA
dc.creator Erdem-Tuncmen, Mukadder
dc.date 2013-12-01T01:00:00Z
dc.date.accessioned 2021-12-03T11:20:13Z
dc.date.available 2021-12-03T11:20:13Z
dc.identifier 39291e18-f538-4590-8182-18dae0e20f72
dc.identifier 10.1007/s10847-012-0220-y
dc.identifier https://avesis.sdu.edu.tr/publication/details/39291e18-f538-4590-8182-18dae0e20f72/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/90945
dc.description New organocobaloxime derivatives of the types [Co(HL)(2)(All)X], [CoL2(All)XB2F4] and [CoL2(All)X(Cu(phen))(2)](ClO4)(2) [H2L1 = 4-(4-chlorophenylamino)biphenylglyoxime and H2L2 = 4-(naphthyl-1-amino)biphenylglyoxime; phen = 1,10-phenanthroline; All = Allyl; X = H2O, py (pyridine), APy (acetylpyridine)] were synthesized and characterized by elemental analysis, molar conductance, FT-IR, H-1 NMR and magnetic susceptibility measurements. Trinuclear complexes {CoL2(All)X[Cu(phen)](2)}(ClO4)(2) have planar N-donor heterocyclic base [1,10-phenanthroline (phen)]. The IR spectra indicated that the complexes coordinate through the N atom of the oxime group of each ligand. The magnetic susceptibilities of the complexes indicated that they are diamagnetic (low-spin d (6) octahedral) except trinuclear complex which show a subnormal magnetic moment.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis and characterization of new organocobaloxime derivatives with asymmetric dioxime ligands
dc.type info:eu-repo/semantics/article


Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse

My Account