| dc.creator |
KARİPCİN, FATMA |
|
| dc.creator |
Erdem-Tuncmen, Mukadder |
|
| dc.date |
2013-12-01T01:00:00Z |
|
| dc.date.accessioned |
2021-12-03T11:20:13Z |
|
| dc.date.available |
2021-12-03T11:20:13Z |
|
| dc.identifier |
39291e18-f538-4590-8182-18dae0e20f72 |
|
| dc.identifier |
10.1007/s10847-012-0220-y |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/39291e18-f538-4590-8182-18dae0e20f72/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/90945 |
|
| dc.description |
New organocobaloxime derivatives of the types [Co(HL)(2)(All)X], [CoL2(All)XB2F4] and [CoL2(All)X(Cu(phen))(2)](ClO4)(2) [H2L1 = 4-(4-chlorophenylamino)biphenylglyoxime and H2L2 = 4-(naphthyl-1-amino)biphenylglyoxime; phen = 1,10-phenanthroline; All = Allyl; X = H2O, py (pyridine), APy (acetylpyridine)] were synthesized and characterized by elemental analysis, molar conductance, FT-IR, H-1 NMR and magnetic susceptibility measurements. Trinuclear complexes {CoL2(All)X[Cu(phen)](2)}(ClO4)(2) have planar N-donor heterocyclic base [1,10-phenanthroline (phen)]. The IR spectra indicated that the complexes coordinate through the N atom of the oxime group of each ligand. The magnetic susceptibilities of the complexes indicated that they are diamagnetic (low-spin d (6) octahedral) except trinuclear complex which show a subnormal magnetic moment. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Synthesis and characterization of new organocobaloxime derivatives with asymmetric dioxime ligands |
|
| dc.type |
info:eu-repo/semantics/article |
|