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Product operator theory for spin-5/2 nuclei: Application to 2D J-resolved NMR spectroscopy

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dc.creator Tokatli, A
dc.creator Bahceli, S
dc.creator Gencten, A
dc.date 2003-01-01T01:00:00Z
dc.date.accessioned 2021-12-03T11:29:06Z
dc.date.available 2021-12-03T11:29:06Z
dc.identifier 598a997e-0d9a-4a88-b0d1-6acc948a83b4
dc.identifier 10.1081/sl-120026611
dc.identifier https://avesis.sdu.edu.tr/publication/details/598a997e-0d9a-4a88-b0d1-6acc948a83b4/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/92021
dc.description Product operator theory is a simple quantum mechanical method that has often been used to analytically describe multi-pulse NMR experiments for weakly coupled spin systems. Considering the existence of 2D-J resolved NMR spectra of aqueous solutions containing S = 5/2 nuclear spins, the product operator formalism has been extended to the weakly coupled IS (I = 1/2, S = 5/2) spin system. The evolution of I., I-Y, IXSZ and IYSZ product operators under spin-spin coupling Hamiltonian are given here. The analytical results obtained are applied to the well-known gated decoupler pulse sequence for heteronuclear 2D-J resolved NMR spectroscopy.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Product operator theory for spin-5/2 nuclei: Application to 2D J-resolved NMR spectroscopy
dc.type info:eu-repo/semantics/article


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