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Bis[N-(2,6-dimethylphenyl)amino-glyoximato-N,N']nickel(II)

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dc.creator Ercan, F
dc.creator Gulce, A
dc.creator Macit, M
dc.creator Ulku, D
dc.date 1996-11-15T01:00:00Z
dc.date.accessioned 2021-12-03T11:29:33Z
dc.date.available 2021-12-03T11:29:33Z
dc.identifier 61ccb9d9-efc5-4497-bdf8-c59f2eefde0b
dc.identifier 10.1107/s0108270196009407
dc.identifier https://avesis.sdu.edu.tr/publication/details/61ccb9d9-efc5-4497-bdf8-c59f2eefde0b/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/92197
dc.description The title compound consists of discrete centrosymmetric [Ni(C10H12N3O2)(2)] molecules. The coordination around the Ni atom is square planar, involving four oxime N atoms of two chelating C2H2N2O2 groups. The oxime O atoms are linked by an intramolecular hydrogen bond [O ... O 2.546 (2) Angstrom] The Ni-N distances are 1.891 (2) and 1.846 (2) Angstrom, and the N-Ni-N angle within the NiC2N2 chelate ring is 82.75 (8)degrees. In the central portion of the molecule, the C=N distances are equal [1.297(3) and 1.298(3) Angstrom], while the two N-O distances are different [1.303 (3) and 1.386 (3) Angstrom].
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Bis[N-(2,6-dimethylphenyl)amino-glyoximato-N,N']nickel(II)
dc.type info:eu-repo/semantics/article


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