| dc.creator |
Sevindir, HC |
|
| dc.date |
2001-01-01T01:00:00Z |
|
| dc.date.accessioned |
2021-12-03T11:30:45Z |
|
| dc.date.available |
2021-12-03T11:30:45Z |
|
| dc.identifier |
7723150c-1040-4a00-b751-7b6d6b25eb31 |
|
| dc.identifier |
10.1081/sim-100001936 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/7723150c-1040-4a00-b751-7b6d6b25eb31/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/92735 |
|
| dc.description |
The reaction of anti-chloro(p-nitrophenyl)glyoxime (CPN-PGH(2)) with thiophenol, 4-methylthiophenol and 4-methoxythiophenol in ethanol between -5 degrees and 10 degreesC gives unsymmetrical vic-dioximes, designated as thiophenolo-p-nitrophenylglyoxime [(LH2)-H-1], 4-methyl-thiophenolo-p-nitrophenylglyoxime [(LH2)-H-2], and 4-methoxythiophenolo-p-nitro-phenylglyoxime [(LH2)-H-3]. The Ni(II) and Cu(II) complexes of these ligands were prepared and are proposed to be square-planar, while the also prepared Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. The structural assignments are supported by H-1 NMR, IR, and elemental analyses. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Synthesis and complex formation of substituted thio-p-nitrophenylglyoximes of unsymmetrical vic-dioximes |
|
| dc.type |
info:eu-repo/semantics/article |
|