| dc.creator |
Sarikurkcu, Cengiz |
|
| dc.creator |
Kazar, Didem |
|
| dc.creator |
Orhan, Nil |
|
| dc.creator |
FIRINCI, ERKAN |
|
| dc.creator |
SÖYLEYİCİ, HAKAN CAN |
|
| dc.creator |
Gokcen, Ceren |
|
| dc.creator |
AYGÜN, MUHİTTİN |
|
| dc.creator |
GİZİROĞLU, EMRAH |
|
| dc.date |
2013-10-01T00:00:00Z |
|
| dc.date.accessioned |
2021-12-03T11:32:04Z |
|
| dc.date.available |
2021-12-03T11:32:04Z |
|
| dc.identifier |
8f65a8c5-7a1f-49d5-a412-c8c8cb6d8e53 |
|
| dc.identifier |
10.1016/j.inoche.2013.09.013 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/8f65a8c5-7a1f-49d5-a412-c8c8cb6d8e53/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/93295 |
|
| dc.description |
o-Hydroxybenzoyl hydrazine and p-hydroxybenzoyl hydrazine react with 1,3-dimethyl-5-acetyl-barbituric acid in ethanol to give H2L1 (85% yield) and H2L2 (91% yield) respectively. The copper(II) complexes with DMSO adducts, [Cu(L-1)(DMSO)] and [Cu(L-2)(DMSO)], were prepared by the stoichiometric reaction of the CuCl2 center dot 5H(2)O with the H2L1 and H2L2 in a molar ratio (M:L) of 1:1 in DMSO/water mixture. All compounds have been fully characterized using conventional spectroscopic techniques. X-ray structure analysis was carried out on the [Cu(L-1)(DMSO)] which crystallizes in the triclinic P-1 space group. In addition, both ligands were applied several antioxidant assays including total antioxidant activity by phosphomolybdate, ferric reducing antioxidant power (FRAP) and scavenging activity on 1,1-diphenyl-2-picrylhydrazyl (DPPH). The results from antioxidant assays have shown that both ligands have excellent activities. (C) 2013 Elsevier B.V. All rights reserved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Synthesis, characterization and antioxidant activity of new dibasic tridentate ligands: X-ray crystal structures of DMSO adducts of 1,3-dimethyl-5-acetyl-barbituric acid o-hydroxybenzoyl hydrazone copper(II) complex |
|
| dc.type |
info:eu-repo/semantics/article |
|