| dc.creator |
KANTAR, CİHAN |
|
| dc.creator |
ŞAŞMAZ, SELAMİ |
|
| dc.creator |
Mert, Firdevs |
|
| dc.date |
2011-09-01T00:00:00Z |
|
| dc.date.accessioned |
2021-12-03T11:32:27Z |
|
| dc.date.available |
2021-12-03T11:32:27Z |
|
| dc.identifier |
95a89a6b-4333-44a7-b27f-cbeeb21ac5f7 |
|
| dc.identifier |
10.1016/j.jorganchem.2011.05.014 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/95a89a6b-4333-44a7-b27f-cbeeb21ac5f7/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/93430 |
|
| dc.description |
The new metallophthalocyanines (Co, Ni, Cu, and Zn) substituted with azo compound containing eugenol moiety are described. Firstly, azo compound (I) containing eugenol moiety was synthesized by treating eugenol with p-hydroxyaniline. Then phthalonitrile compound (1) was synthesized by microwave-assisted synthesis method. The purification of phthalonitrile compound (1) was carried out by column chromatographic separation. Intramolecular hydrogen bonding in the azo compound (I) prevent base-catalyzed nucleophilic aromatic substitution of OH group belongs eugenol. At the last step, metallophthalocyanines (1a, 1b, 1c, and 1d) were synthesized by the microwave irradiation. The microwave-assisted synthesis method reduces reaction times and enhances the yield of the reactions. All phthalocyanine compounds are soluble in DMF and DMSO. The structures were confirmed by elemental analysis, H-1 NMR, C-13 NMR, UV/Vis, IR and Mass spectra. (C) 2011 Elsevier B. V. All rights reserved. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
Microwave-assisted synthesis and characterization of phthalocyanines substituted with azo compound containing eugenol moiety |
|
| dc.type |
info:eu-repo/semantics/article |
|