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A DINUCLEAR OXYGEN-BRIDGED SCHIFF BASE IRON(III) COMPLEX DERIVED FROM N,N'-bis(4-METHOXY-2-HYDROXYBENZYLIDENE)2,2-DIMETHYLPROPANE-1,3-DIAMINE

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dc.creator Kurtaran, R.
dc.creator Karahan, A.
dc.creator Yahsi, Y.
dc.creator Gungor, E.
dc.creator Kara, H.
dc.date 2016-07-01T00:00:00Z
dc.date.accessioned 2021-12-03T11:46:32Z
dc.date.available 2021-12-03T11:46:32Z
dc.identifier a5fe520d-4e4f-446c-981b-05c8c546477b
dc.identifier 10.1134/s0022476616040156
dc.identifier https://avesis.sdu.edu.tr/publication/details/a5fe520d-4e4f-446c-981b-05c8c546477b/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/93944
dc.description The mu-oxo-bridged Fe(III) dimer complex [{Fe(4-MeOL1)}(2)(mu-O)]center dot HOCH3, (H-2-4-MeOL1 = N,N'-bis(4-methoxy- 2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine), 1 is synthesized and characterized by single crystal X-ray diffraction. Complex 1 contains a [{Fe(4-MeOL1)}(2)(mu-O)] dimeric unit with a methanol solvent molecule of crystallization. Each Fe(III) ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Fe(III) atom is coordinated by two N and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O2- ion, linking another Fe(III) ion in the complex. There are intermolecular C-H. O and C-H....pi interactions among the dinuclear complexes.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title A DINUCLEAR OXYGEN-BRIDGED SCHIFF BASE IRON(III) COMPLEX DERIVED FROM N,N'-bis(4-METHOXY-2-HYDROXYBENZYLIDENE)2,2-DIMETHYLPROPANE-1,3-DIAMINE
dc.type info:eu-repo/semantics/article


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