| dc.creator |
Sevindir, HC |
|
| dc.date |
1996-01-01T01:00:00Z |
|
| dc.date.accessioned |
2021-12-03T11:47:07Z |
|
| dc.date.available |
2021-12-03T11:47:07Z |
|
| dc.identifier |
af80c5aa-d064-477d-b1e7-387482aadc9d |
|
| dc.identifier |
10.1080/00945719608005129 |
|
| dc.identifier |
https://avesis.sdu.edu.tr/publication/details/af80c5aa-d064-477d-b1e7-387482aadc9d/oai |
|
| dc.identifier.uri |
http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/94289 |
|
| dc.description |
In this study, anti-chloro(p-nitrophenyl)glyoxime (CPNPGH(2)) has been synthesized by chlorination of anti-p-nitrophenylglyoxime. The reaction of CPNPGH(2) with suitable aryl or arylkalyamines in ethanol between -5 degrees C and 15 degrees C gives unsymmetrical dioximes, namely, o-toluidino-p-nitrophenylglyoxime (C15H14N4O4), l-naphthylamino-p-nitrophenylglyoxime (C18H14N4O4), biphenyl-4-amino-4'-amino-p-nitrophenylglyoxime (C20H17N5O4) and N-(2-methylpyridyl) amino-p-nitrophenylglyoxime (C14H13N5O4) The Cu(II) and Ni(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. H-1 NMR, IR spectra and elemental analyses data are given. |
|
| dc.language |
eng |
|
| dc.rights |
info:eu-repo/semantics/closedAccess |
|
| dc.title |
The synthesis of four new unsymmetrical vic-dioximes and their complexes with some transition metals |
|
| dc.type |
info:eu-repo/semantics/article |
|