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Calorimetric study of the alpha-tocopherol solubility in reversed AOT micelles

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dc.creator Wilczura-Wachnik, H.
dc.creator Myslinski, A.
dc.creator Yavuz, A. G.
dc.date 2008-03-15T01:00:00Z
dc.date.accessioned 2021-12-03T11:54:52Z
dc.date.available 2021-12-03T11:54:52Z
dc.identifier c50b2340-eb26-4e5c-b29b-e110cc71958f
dc.identifier 10.1016/j.jcis.2007.11.044
dc.identifier https://avesis.sdu.edu.tr/publication/details/c50b2340-eb26-4e5c-b29b-e110cc71958f/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/94757
dc.description The experimental data of heat of mixing (Q) for heterogeneous system alpha-tocopherol/AOT/n-heptane with and without water at 25 degrees C are presented. The Q dependence on AOT (sodium bis (2-ethylhexyl) sulfosuccinate) concentration, and R parameter defined as R = [H2O]/[AOT] with flow calorimetric method were investigated, Using the D'Aprano model (which is formally identical to that used earlier by Magid et al.) the binding constant (K), the distribution constant of a-tocopherol (K-distr) between hydrocarbon and the micellar phase, and the standard enthalpy of transfer (Delta H-tr(0)) of alpha-tocopherol from the hydrocarbon to AOT reversed micelles were calculated. The solubility of a-tocopherol in AOT reversed micelles explored with the calorimetric technique was compared to the literature data obtained respectively with UV spectrophotometry for reversed micelles and by other techniques for the phospholipid bilayer. (C) 2007 Elsevier Inc. All rights reserved.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Calorimetric study of the alpha-tocopherol solubility in reversed AOT micelles
dc.type info:eu-repo/semantics/article


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