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Synthesis and characterization of 4-arylaminobiphenylglyoximes and their complexes

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dc.creator Arabali, Filiz
dc.creator Karipcin, Fatma
dc.creator Karatas, I.
dc.date 2006-09-01T00:00:00Z
dc.date.accessioned 2021-12-03T12:03:20Z
dc.date.available 2021-12-03T12:03:20Z
dc.identifier d65a83ba-47fc-4c14-a37f-fb469a12722e
dc.identifier https://avesis.sdu.edu.tr/publication/details/d65a83ba-47fc-4c14-a37f-fb469a12722e/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/95157
dc.description 4-Chloroacetylbiphenyl has been synthesized by Friedel-Crafts reaction between biphenyl and chloroacetyl chloride in the presence of AlCl3 catalyst. The nitrosation reaction of this compound gave 4-biphenylhydroxamyl chloride (HL). Subsequently, 4-biphenylchloroglyoxime (H2L) was prepared by the reaction of 4-biphenylhydroxamyl chloride and hydroxylamine hydrochloride. Then, six new substituted 4-biphenylaminoglyoximes (H2Lx) have been synthesized from 4-biphenylchloroglyoxime and the corresponding amines. A series of M(II)-dioxime complexes of the type [M(HLx)(2)] or [M(HLx)(2) (H2O)(2)] [M(II)=Co(II), Ni(II), Cu(II)] have been synthesized and characterized by FT-IR, H-1 NMR spectral studies, elemental analysis, AAS and magnetic susceptibility measurements.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis and characterization of 4-arylaminobiphenylglyoximes and their complexes
dc.type info:eu-repo/semantics/article


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